Event slated for Oct. 19 in Mexico City.

Mexican rock band Molotov and "Nacho Libre" actress Ana de la Reguera will host Los Premios MTV Latinoamerica Oct. 19.

Robbie Williams, Mexican electronic act Belanova, Nelly Furtado, Evanescence and Julieta Venegas will perform during the live broadcast from Mexico City's Palacio de los Deportes. It will be the first time the awards show, which has been held in Miami since 2002, will be hosted by a Latin American country.

The ceremony will air on MTV Latin America in at least 24 countries, and will also be shown on MTV, MTV2 and MTV Tr3s in the US.