From the start, Williams attracted a good deal of attention with her fiery red hair, unique wardrobe, and vocal talent. Her singing chops earned her a string of cameos on other albums, including October Falls A Season in Hell and Say Anythings In Defense of the Genre, while her looks won her the honor of Kerrangs Second Sexiest Female in 2007. Williams remained focused on Paramore, though, whose 2007 sophomore effort Riot! went platinum in the U.S. and achieved gold status in four other countries. The band hit the road in support of the records release; during the lengthy tour that followed, Williams and Josh Farro (who had been dating for much of the bands existence) broke things off, and the band introduced newcomer Taylor York to the lineup. Paramore also charted another hit with their contribution to the Twilight soundtrack, Decode.
Williams made more guest appearances in 2009, including a performance alongside her new boyfriend, Chad Gilbert, on the New Found Glory track Tangled Up. Meanwhile, Paramore wrapped up work on a third album, Brand New Eyes, and released it that September, where it debuted at number two and quickly went gold. Also appearing that autumn was Williams first solo composition, Teenagers, which was included on the movie soundtrack to Jennifers Body. One year later, Williams returned to the upper reaches of the charts with Airplanes, a collaboration with hip-hop artist B.o.B. that peaked at number two in America and topped the charts in England. ~ Andrew Leahey, Rovi